ENE REACTION OF 2-(ALKYLTHIO)ALLYL SILYL ETHER INVOLVING A CHIRALITY TRANSFER

被引：24

作者：

TANINO, K ^{[1
]}

SHODA, H ^{[1
]}

NAKAMURA, T ^{[1
]}

KUWAJIMA, I ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,DEPT CHEM,TOKYO 152,JAPAN

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 10期

关键词：

D O I：

10.1016/S0040-4039(00)91616-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A highly enantio-selective ene reaction was developed on the bases of chirality transfer. Under the influence of Me2AlCl, the reactions of various aldehydes with (S)-3-(tert-butyldimethylsiloxy)-2-(ethylthio)-1-butene which was easily prepared from (S)-ethyl lactate afforded the optically active adducts in high ee.

引用

页码：1337 / 1340

页数：4

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