CHEMICALLY MODIFIED ELECTRODE FOR THE SIMULTANEOUS DETERMINATION OF TRACE-METALS AND SPECIATION ANALYSIS

被引：50

作者：

AGRAZ, R ^{[1
]}

SEVILLA, MT ^{[1
]}

HERNANDEZ, L ^{[1
]}

机构：

[1] UNIV AUTONOMA MADRID,DEPT ANALYT CHEM & INSTRUMENTAL ANAL,E-28049 MADRID,SPAIN

来源：

ANALYTICA CHIMICA ACTA | 1993年 / 273卷 / 1-2期

关键词：

VOLTAMMETRY; CADMIUM; CARBON PASTE ELECTRODE; COPPER; LEAD; MERCURY; PRECONCENTRATION; SPECIATION; TRACE METALS; ZINC;

D O I：

10.1016/0003-2670(93)80159-I

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A modified carbon paste electrode was used for the simultaneous determination of Zn, Cd, Pb, Cu and Hg. Trace metal preconcentration was effected by selective retention on Amberlite IRC 718 chelating resin as an electrode modifier, with subsequent measurement by differential-pulse voltammetry. Peak potentials for he reoxidation of these metals occur at - 1.05, - 0.80, - 0.48, - 0.24 and 0.06 V, respectively, allowing determinations at the mug l-1 level. Several metal ratios were studied in order to determine the influence of each metal on the determination of the others. The influence of other substances was also studied to determine the potential of the method for speciation analysis studies.

引用

页码：205 / 212

页数：8

共 27 条

[1] AGRAZ R, 1991, ELECTROANAL, V3, P993
[2] [Anonymous], 1985, STRIPPING ANAL PRINC
[3] VOLTAMMETRIC DETERMINATION OF TRACES OF NICKEL(II) AT A CHEMICALLY MODIFIED ELECTRODE BASED ON DIMETHYLGLYOXIME-CONTAINING CARBON PASTE
BALDWIN, RP
CHRISTENSEN, JK
KRYGER, L
[J]. ANALYTICAL CHEMISTRY, 1986, 58 (08) : 1790 - 1798
[4] CYCLIC AND STRIPPING VOLTAMMETRY OF MERCURY AT IMPREGNATED GRAPHITE ELECTRODE IN CHLORIDE AND THIOCYANATE MEDIA
BILEWICZ, R
STOJEK, Z
KUBLIK, Z
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1979, 96 (01): : 29 - 44
[5] CALCULATION OF THE SURFACE CONCENTRATION OF THE OXIDIZED METAL DURING THE STRIPPING STEP IN THE ANODIC-STRIPPING TECHNIQUES AND ITS INFLUENCE ON SPECIATION MEASUREMENTS IN NATURAL-WATERS
BUFFLE, J
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1981, 125 (02): : 273 - 294
[6] Buffle J., 1988, COMPLEXATION REACTIO
[7] CLEN RT, 1978, ANAL CHEM, V50, P102
[8] DETERMINATION OF LABILITIES OF SOLUBLE TRACE-METAL SPECIES IN AQUEOUS ENVIRONMENTAL-SAMPLES BY ANODIC-STRIPPING VOLTAMMETRY AND CHELEX COLUMN AND BATCH METHODS
FIGURA, P
MCDUFFIE, B
[J]. ANALYTICAL CHEMISTRY, 1980, 52 (09) : 1433 - 1439
[9] ANODIC-STRIPPING VOLTAMMETRY WITH MEDIUM EXCHANGE IN TRACE-ELEMENT SPECIATION
FLORENCE, TM
MANN, KJ
[J]. ANALYTICA CHIMICA ACTA, 1987, 200 (01) : 305 - 312
[10] REMOVAL OF TRACE-METALS FROM SEAWATER BY A CHELATING RESIN
FLORENCE, TM
BATLEY, GE
[J]. TALANTA, 1975, 22 (02) : 201 - 204

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