DATABASE ANALYSIS OF AU ... AU INTERACTIONS

被引：167

作者：

PATHANENI, SS ^{[1
]}

DESIRAJU, GR ^{[1
]}

机构：

[1] UNIV HYDERABAD,SCH CHEM,HYDERABAD 500134,ANDHRA PRADESH,INDIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 02期

关键词：

D O I：

10.1039/dt9930000319

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The geometry of gold-gold interactions in a group of 693 gold-containing crystal structures has been examined using data from the Cambridge Structural Database. These contacts occur in the range 2.50-4.00 angstrom. Intermolecular Au...Au contacts are formed by compounds of the type AuXY (X, Y = any element) with the X-Au-Au-Y conformation being either staggered or eclipsed. Clusters of the type Au(n)Z (where Z is any element including Au) are characterised by a large number of short gold-gold contacts reflecting an approach towards Au0 in the interior of the cluster.

引用

页码：319 / 322

页数：4

共 29 条

[11] Jones P. G., 1986, GOLD BULL, V19, P46
[12] GOLD COMPLEXES WITH SELENIUM LIGANDS .4. PREPARATION, CRYSTAL-STRUCTURES AND REACTIONS OF PHOSPHINE(SELENOUREA)GOLD(I) COMPLEXES
JONES, PG
THONE, C
[J]. CHEMISCHE BERICHTE-RECUEIL, 1991, 124 (12): : 2725 - 2729
[13] GOLD COMPLEXES WITH SELENIUM LIGANDS .1. PREPARATION AND CRYSTAL-STRUCTURES OF PHENYLSELENOLATO-GOLD(I) COMPLEXES
JONES, PG
THONE, C
[J]. CHEMISCHE BERICHTE, 1990, 123 (10) : 1975 - 1978
[14] MU-3-SULPHIDO-TRIS[TRIPHENYLPHOSPHINEGOLD(I)]HEXAFLUOROPHOSPHATE
JONES, PG
SHELDRICK, GM
HADICKE, E
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1980, 36 (NOV): : 2777 - 2779
[15] LAURITSEN LN, 1985, J COMPUT CHEM, V6, P216
[16] MOLECULAR-ORBITAL ANALYSIS OF MONO-CARBIDO-GOLD AND DI-CARBIDO-GOLD CLUSTER COMPOUNDS
MINGOS, DMP
KANTERS, RPF
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 384 (03) : 405 - 415
[17] Pitzer K. S., 1979, ACCOUNTS CHEM RES, V12, P271
[18] RELATIVITY AND THE PERIODIC SYSTEM OF ELEMENTS
PYYKKO, P
DESCLAUX, JP
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1979, 12 (08) : 276 - 281
[19] ABINITIO CALCULATIONS ON THE (CLAUPH3)2 DIMER WITH RELATIVISTIC PSEUDOPOTENTIAL - IS THE AUROPHILIC ATTRACTION A CORRELATION EFFECT
PYYKKO, P
ZHAO, YF
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (05): : 604 - 605
[20] AUROPHILICITY AS CONCERTED EFFECT - RELATIVISTIC MO CALCULATIONS ON CARBON-CENTERED GOLD CLUSTERS
ROSCH, N
GORLING, A
ELLIS, DE
SCHMIDBAUR, H
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (10): : 1357 - 1359

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