THE REACTION OF DIMETHYL DIOXIRANE WITH DIAZOMETHYLPHOSPHONATES - THE FIRST SYNTHESIS OF A FORMYLPHOSPHONATE HYDRATE

被引：13

作者：

HAMILTON, R ^{[1
]}

MCKERVEY, MA ^{[1
]}

RAFFERTY, MD ^{[1
]}

WALKER, BJ ^{[1
]}

机构：

[1] QUEENS UNIV BELFAST,SCH CHEM,BELFAST BT9 5AG,NORTH IRELAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 01期

关键词：

D O I：

10.1039/c39940000037

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Formylphosphonate hydrate 8, synthesized for the first time by the reaction of diethyl diazomethylphosphonate with dimethyl dioxirane (DMD), reacts with primary amines to provide imines 9 and 10; compound 9 is also prepared by the reaction of the anion of diethyl methylenebisphosphonate with nitrosobenzene.

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页码：37 / 38

页数：2

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