STEREOCHEMISTRY OF ALLYLIC ALKYLATION OF THE TETRACARBONYLIRON COMPLEXES OF (R)-1-ACETYL-5-ISOPROPOXY-3-PYRROLIN-2-ONE

被引：26

作者：

KOOT, WJ ^{[1
]}

HIEMSTRA, H ^{[1
]}

SPECKAMP, WN ^{[1
]}

机构：

[1] UNIV AMSTERDAM,DEPT ORGAN CHEM,NIEUWE ACHTERGRACHT 129,1018 WS AMSTERDAM,NETHERLANDS

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 02期

关键词：

D O I：

10.1039/c39930000156

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The two diastereoisomeric title complexes react with allyltrimethylsilane in the presence of BF3.Et2O to give nucleophilic substitution at C-5 to the corresponding 5-allyl derivatives; the reaction of the cis-complex proceeds slowly and with predominant inversion, whereas the trans-complex reacts quickly and with complete retention of configuration at C-5.

引用

页码：156 / 158

页数：3

共 13 条

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