SYNTHESIS AND REACTIVITY OF THE PHOSPHINIDENE CLUSTER COMPLEX FE3(CO)9(MU-3-PH)2 - A VERSATILE CLUSTER BUILDING-BLOCK

被引：10

作者：

BAUTISTA, MT ^{[1
]}

JORDAN, MR ^{[1
]}

WHITE, PS ^{[1
]}

SCHAUER, CK ^{[1
]}

机构：

[1] UNIV N CAROLINA,DEPT CHEM,CHAPEL HILL,NC 27599

来源：

INORGANIC CHEMISTRY | 1993年 / 32卷 / 24期

关键词：

D O I：

10.1021/ic00076a003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A rare example of a P-H phosphinidene cluster complex, Fe3(CO)9(mu3-PH)2 (1), is prepared by hydrolysis of the silylphosphinidene precursor, Fe3-(CO)9[mu3-PSi(i-Pr)3]2. A range of reactivity is accessible at the mu3-PH site of this intact molecular cluster including reactions of electrophiles at phosphorus following removal of a phosphorus-bound proton in 1 as well as reactions of nucleophiles at phosphorus following, conversion of the P-H moiety to a P-Cl functional group using CCl4 as a chlorination agent.

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页码：5429 / 5430

页数：2

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