SYNTHESIS AND REACTIVITY OF THE PHOSPHINIDENE CLUSTER COMPLEX FE3(CO)9(MU-3-PH)2 - A VERSATILE CLUSTER BUILDING-BLOCK

被引：10

作者：

BAUTISTA, MT ^{[1
]}

JORDAN, MR ^{[1
]}

WHITE, PS ^{[1
]}

SCHAUER, CK ^{[1
]}

机构：

[1] UNIV N CAROLINA,DEPT CHEM,CHAPEL HILL,NC 27599

来源：

INORGANIC CHEMISTRY | 1993年 / 32卷 / 24期

关键词：

D O I：

10.1021/ic00076a003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A rare example of a P-H phosphinidene cluster complex, Fe3(CO)9(mu3-PH)2 (1), is prepared by hydrolysis of the silylphosphinidene precursor, Fe3-(CO)9[mu3-PSi(i-Pr)3]2. A range of reactivity is accessible at the mu3-PH site of this intact molecular cluster including reactions of electrophiles at phosphorus following removal of a phosphorus-bound proton in 1 as well as reactions of nucleophiles at phosphorus following, conversion of the P-H moiety to a P-Cl functional group using CCl4 as a chlorination agent.

引用

收藏

页码：5429 / 5430

页数：2

相关论文

共 32 条

[21] ISOLATION AND X-RAY STRUCTURE OF [LI2(MU-3-TERT-BU2P)(MU-3-TERT-BU2P)(C4H8O)]2 CONTAINING A STAGGERED, PLANAR LI4 UNIT - THE 1ST STRUCTURALLY CHARACTERIZED ALKALI-METAL DIORGANOPHOSPHIDE [J].

JONES, RA ;

STUART, AL ;

WRIGHT, TC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (25) :7459-7460

[22] FE3-TRIANGLE OPENING AND CLOSING BY A SINGLE 2-ELECTRON PROCESS IN THE BICAPPED TRIIRON CLUSTERS FE3(CO)9(MU-3-PMLN)2 (MLN = CPFE(CO)2, CPMN(CO)2) [J].

KOIDE, Y ;

BAUTISTA, MT ;

WHITE, PS ;

SCHAUER, CK .

INORGANIC CHEMISTRY, 1992, 31 (18) :3690-3692

[23] DIHALOGEN PHOSPHANE COMPOUNDS AS METALORGANIC ELEMENTS [J].

LANG, H ;

ZSOLNAI, L ;

HUTTNER, G .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 282 (01) :23-51

[24] SYNTHESIS OF THE FUNCTIONALIZED CLUSTER (CH=CH2C5H4)CP3FE4(CO)4 AND ITS INCORPORATION INTO POLY(METHYL METHACRYLATE) [J].

MASSA, MA ;

RAUCHFUSS, TB .

CHEMISTRY OF MATERIALS, 1991, 3 (05) :788-790

[25] ACTIVATION OF TRIIRON CLUSTERS BY ELECTRON-TRANSFER - RADICAL-ANIONS AND DIANIONS OF FE3(MU-3-PPH)2(CO)9 AND ITS DERIVATIVES [J].

OHST, HH ;

KOCHI, JK .

INORGANIC CHEMISTRY, 1986, 25 (12) :2066-2074

[26] NOVEL REDOX PROPERTIES OF THE PARAMAGNETIC HEXANUCLEAR NIOBIUM CLUSTER HALIDE NB6CL18(3-) AND THE PREPARATION, STRUCTURES, AND CONDUCTING AND MAGNETIC-PROPERTIES OF ITS ONE-DIMENSIONAL MIXED-VALENCE TETRAMETHYLTETRA(SELENA AND THIA)FULVALENIUM SALTS - [TMTSF AND TMTTF]5[NB6CL18].(CH2CL2)0.5 [J].

PENICAUD, A ;

BATAIL, P ;

COULON, C ;

CANADELL, E ;

PERRIN, C .

CHEMISTRY OF MATERIALS, 1990, 2 (02) :123-132

[27] TRANSITION-METAL PHOSPHIDO COMPLEXES .9. P-FUNCTIONAL HETEROCYCLIC MANGANESE PHOSPHORUS 4-MEMBERED AND 6-MEMBERED RING COMPLEXES [J].

SCHAFER, H ;

ZIPFEL, J ;

GUTEKUNST, B ;

LEMMERT, U .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1985, 529 (10) :157-172

[28] A PROTECTED METALLOPHOSPHINE LIGAND - SYNTHESIS, STRUCTURE, AND REACTIVITY OF THE SILYLPHOSPHINIDENE CLUSTER (MU-H)2FE3(CO)9[MU-3-PSI(I-PR3)] [J].

SUNICK, DL ;

WHITE, PS ;

SCHAUER, CK .

ORGANOMETALLICS, 1993, 12 (02) :245-247

[29] PHOTOCHEMICALLY REACTIVE POLYMERS - SYNTHESIS AND CHARACTERIZATION OF POLYURETHANES CONTAINING CP2MO2(CO)6 OR CP2FE2(CO)4 MOLECULES ALONG THE POLYMER BACKBONE [J].

TENHAEFF, SC ;

TYLER, DR .

ORGANOMETALLICS, 1991, 10 (02) :473-482

[30] INTRAMOLECULAR REDOX CHEMISTRY OF MOLECULES WITH ALKYNE AND CCO3 CLUSTER FUNCTIONALITIES - ELECTRONIC INTERACTION AND STRUCTURAL ISOMERISM IN REDUCED CLUSTERS WITH MULTIPLE REDOX CENTERS [J].

WORTH, GH ;

ROBINSON, BH ;

SIMPSON, J .

ORGANOMETALLICS, 1992, 11 (11) :3863-3874

← 1 2 3 4 →