FLUCTUATION PHENOMENA AT A 1ST-ORDER PHASE-TRANSITION

被引：14

作者：

HENDERSON, JR ^{[1
]}

VANSWOL, F ^{[1
]}

机构：

[1] UNIV ILLINOIS, DEPT CHEM ENGN, URBANA, IL 61801 USA

来源：

JOURNAL OF PHYSICS-CONDENSED MATTER | 1990年 / 2卷 / 19期

关键词：

D O I：

10.1088/0953-8984/2/19/020

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

The authors report the observation of a fluctuation-induced first order phase transition between two states of adsorption at a wall-liquid interface. WDA density functional theory modified to enable input of the measured bulk equation of state is used to confirm the critical nature of the mean-field transition. MD computer simulation results show a first-order phase transition associated with dramatic collective fluctuations in the amount of adsorbed fluid. The qualitative appearance of the large-scale fluctuation events is described.

引用

页码：4537 / 4542

页数：6

共 14 条

[11] FREE-ENERGY DENSITY FUNCTIONAL FOR HARD-SPHERES
TARAZONA, P
[J]. PHYSICAL REVIEW A, 1985, 31 (04): : 2672 - 2679
[12] WETTING AND DRYING TRANSITIONS AT A FLUID-WALL INTERFACE - DENSITY-FUNCTIONAL THEORY VERSUS COMPUTER-SIMULATION
VANSWOL, F
HENDERSON, JR
[J]. PHYSICAL REVIEW A, 1989, 40 (05): : 2567 - 2578
[13] WETTING AT A FLUID WALL INTERFACE - COMPUTER-SIMULATION AND EXACT STATISTICAL SUM-RULES
VANSWOL, F
HENDERSON, JR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1986, 82 : 1685 - 1699
[14] Wilson K. G., 1974, Physics Reports. Physics Letters Section C, V12c, P75, DOI 10.1016/0370-1573(74)90023-4

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