REGIOSELECTIVE ESTERIFICATION OF DIOLS AND TRIOLS WITH LIPASES IN ORGANIC-SOLVENTS

被引：24

作者：

PARMAR, VS

SINHA, R

BISHT, KS

GUPTA, S

PRASAD, AK

TANEJA, P

机构：

[1] Department of Chemistry, University of Delhi, Delhi

来源：

TETRAHEDRON | 1993年 / 49卷 / 19期

关键词：

D O I：

10.1016/S0040-4020(01)89922-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Lipases from porcine pancreas (PPL) and Candida cylindracea (CCL) in different organic solvents allow discrimination of the primary and secondary hydroxyl groups, and also between two primary hydroxyl groups towards acylation with 2,2,2-trifluoroethyl butyrate in diols and triols with high regioselectivity.

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页码：4107 / 4116

页数：10

相关论文

共 14 条

[1] HYDROLASES IN ORGANIC-SYNTHESIS - PREPARATION OF ENANTIOMERICALLY PURE COMPOUNDS [J].

ADER, U ;

ANDERSCH, P ;

BERGER, M ;

GOERGENS, U ;

SEEMAYER, R ;

SCHNEIDER, M .

PURE AND APPLIED CHEMISTRY, 1992, 64 (08) :1165-1170

[2] LIPASE CATALYZED REGIOSELECTIVE AND ENANTIOSELECTIVE HYDROLYSIS - MOLECULAR RECOGNITION PHENOMENON AND SYNTHESIS OF (R)-DIMORPHECOLIC ACID [J].

BHALERAO, UT ;

DASARADHI, L ;

NEELAKANTAN, P ;

FADNAVIS, NW .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (17) :1197-1198

[3] GENERAL-ASPECTS AND OPTIMIZATION OF ENANTIOSELECTIVE BIOCATALYSIS IN ORGANIC-SOLVENTS - THE USE OF LIPASES [J].

CHEN, CS ;

SIH, CJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (06) :695-707

[4] ENZYMES IN CARBOHYDRATE SYNTHESIS - LIPASE-CATALYZED SELECTIVE ACYLATION AND DEACYLATION OF FURANOSE AND PYRANOSE DERIVATIVES [J].

HENNEN, WJ ;

SWEERS, HM ;

WANG, YF ;

WONG, CH .

JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (21) :4939-4945

[5] ENANTIOSELECTIVITY OF SOME LIPASES - CONTROL AND PREDICTION [J].

HULT, K ;

NORIN, T .

PURE AND APPLIED CHEMISTRY, 1992, 64 (08) :1129-1134

[6] ASYMMETRIC HYDROLYSIS OF ESTERS BY BIOCHEMICAL METHODS .3. ASYMMETRIC HYDROLYSIS OF "(+/-)-1,2-DIACETOXY-3-CHLOROPROPANE AND ITS RELATED-COMPOUNDS WITH LIPASE - SYNTHESIS OF OPTICALLY PURE (S)-PROPRANOLOL [J].

IRIUCHIJIMA, S ;

KOJIMA, N .

AGRICULTURAL AND BIOLOGICAL CHEMISTRY, 1982, 46 (05) :1153-1157

[7] ENZYMES IN ORGANIC-SYNTHESIS [J].

JONES, JB .

TETRAHEDRON, 1986, 42 (13) :3351-3403

[8]

KLIBANOV A M, 1986, Chemtech, V16, P354

[9] PORCINE PANCREATIC LIPASE MEDIATED SELECTIVE ACYLATION OF PRIMARY ALCOHOLS IN ORGANIC-SOLVENTS [J].

RAMASWAMY, S ;

MORGAN, B ;

OEHLSCHLAGER, AC .

TETRAHEDRON LETTERS, 1990, 31 (24) :3405-3408

[10] POLYMERIZED PHOSPHATIDYLCHOLINE VESICLES - SYNTHESIS AND CHARACTERIZATION [J].

REGEN, SL ;

SINGH, A ;

OEHME, G ;

SINGH, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (03) :791-795