ENANTIOSELECTIVE CATALYTIC BORANE REDUCTIONS OF ACHIRAL KETONES - SYNTHESIS AND APPLICATION OF NEW RIGID CATALYSTS PREPARED FROM (R)-PHENYLGLYCINE AND (S)-PHENYLALANINE

被引：19

作者：

DAUELSBERG, C ^{[1
]}

MARTENS, J ^{[1
]}

机构：

[1] UNIV OLDENBURG,FACHBEREICH CHEM,AMMERLANDER HEERSTR 114-118,W-2900 OLDENBURG,GERMANY

来源：

SYNTHETIC COMMUNICATIONS | 1993年 / 23卷 / 15期

关键词：

D O I：

10.1080/00397919308018602

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Enantiocontrolled reduction of prochiral ketones with borane in the presence of homochiral amino alcohols 1 - 4 as enantioselective catalysts afforded the chiral corresponding secondary alcohols in moderate to high (55 to 88 %) optical yields.

引用

页码：2091 / 2099

页数：9

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