THE EXTRACTION OF DYNAMICS FROM SPECTRA IN REGIONS OF MIXED CHAOTIC AND REGULAR MOTION - THE HCN CASE

被引：18

作者：

FARANTOS, SC ^{[1
]}

LLORENTE, JMG ^{[1
]}

HAHN, O ^{[1
]}

TAYLOR, HS ^{[1
]}

机构：

[1] UNIV SO CALIF,DEPT CHEM,LOS ANGELES,CA 90089

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 166卷 / 01期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0009-2614(90)87052-S

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The survival probability recently obtained from a quantum mechanical theoretical SEP spectrum of HCN is approximated by its classical analogue. It is shown that classical mechanics provides an excellent approximation to the quantum survival probability. Analysis of the phase space shows that the motions of the molecule which follow the initial excitation are governed by tori in a resonance zone characterized by a 3:1 resonance between the CN stretching and bending modes. A comparison of the Fourier transform of the correlation function to an experimental low resolution fluorescence spectrum is also made. © 1990.

引用

页码：71 / 76

页数：6

共 26 条

[11] PERIODIC-ORBITS, BIFURCATIONS, AND QUANTUM-MECHANICAL EIGENFUNCTIONS AND SPECTRA
FOUNARGIOTAKIS, M
FARANTOS, SC
CONTOPOULOS, G
POLYMILIS, C
[J]. JOURNAL OF CHEMICAL PHYSICS, 1989, 91 (03) : 1389 - 1402
[12] MOLECULAR OVERTONE BANDWIDTHS FROM CLASSICAL TRAJECTORIES
HELLER, EJ
DAVIS, MJ
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1980, 84 (16) : 1999 - 2001
[13] DIAMAGNETISM OF THE HYDROGEN-ATOM IN THE QUASI-LANDAU REGIME
HOLLE, A
WIEBUSCH, G
MAIN, J
HAGER, B
ROTTKE, H
WELGE, KH
[J]. PHYSICAL REVIEW LETTERS, 1986, 56 (24) : 2594 - 2597
[14] DYNAMICAL INTERPRETATION OF THE HARTLEY-ABSORPTION OSCILLATIONS IN O-3
JOHNSON, BR
KINSEY, JL
[J]. PHYSICAL REVIEW LETTERS, 1989, 62 (14) : 1607 - 1610
[15] ADIABATIC APPROXIMATION AND NONADIABATIC CORRECTIONS IN THE DISCRETE VARIABLE REPRESENTATION - HIGHLY EXCITED VIBRATIONAL-STATES OF TRIATOMIC-MOLECULES
LIGHT, JC
BACIC, Z
[J]. JOURNAL OF CHEMICAL PHYSICS, 1987, 87 (07) : 4008 - 4019
[16] SPECTRA IN THE CHAOTIC REGION - METHODS FOR EXTRACTING DYNAMIC INFORMATION
LLORENTE, JMG
ZAKRZEWSKI, J
TAYLOR, HS
KULANDER, KC
[J]. JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (03) : 1505 - 1518
[17] SPECTRA IN THE CHAOTIC REGION - A CLASSICAL-ANALYSIS FOR THE SODIUM TRIMER
LLORENTE, JMG
TAYLOR, HS
[J]. JOURNAL OF CHEMICAL PHYSICS, 1989, 91 (02) : 953 - 962
[18] CLASSICAL MECHANICAL ANALYSIS OF THE EXPERIMENTAL HIGH-ENERGY SPECTRUM OF THE SODIUM TRIMER MOLECULE
LLORENTE, JMG
TAYLOR, HS
POLLAK, E
[J]. PHYSICAL REVIEW LETTERS, 1989, 62 (18) : 2096 - 2099
[19] A CLASSICAL TRAJECTORY STUDY OF THE PHOTODISSOCIATION SPECTRUM OF H-3+
LLORENTE, JMG
POLLAK, E
[J]. JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (10) : 5406 - 5419
[20] FREQUENCY OPTIMIZED POTENTIAL-ENERGY FUNCTIONS FOR THE GROUND-STATE SURFACES OF HCN AND HCP
MURRELL, JN
CARTER, S
HALONEN, LO
[J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 1982, 93 (02) : 307 - 316

← 1 2 3 →