FORMATION OF NH(C1-PI), NH(A3-PI) AND NCO(A2-SIGMA) IN THE VUV PHOTOLYSIS OF HNCO

被引:18
作者
UNO, K [1 ]
HIKIDA, T [1 ]
HIRAYA, A [1 ]
SHOBATAKE, K [1 ]
机构
[1] INST MOLEC SCI,OKAZAKI,AICHI 444,JAPAN
关键词
D O I
10.1016/0009-2614(90)87136-F
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Photodissociative excitation processes of gaseous HNCO are studied in the wavelength region 107-180 nm using synchrotron radiation as a light source. Fluorescence excitation spectra of the photofragments, NH(c 1Π, A 3Π) and NCO(A 2Σ), are measured under near collision-free conditions. The quantum yields for formation of these excited radicals are also determined. © 1990.
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页码:475 / 479
页数:5
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