STRUCTURAL EVALUATION OF A DIBENZOBICYCLIC PHOSPHORANE - ANOTHER EXAMPLE OF A BERRY EXCHANGE COORDINATE

被引：15

作者：

CONTRERAS, R

MURILLO, A

JOSEPHNATHAN, P

机构：

[1] Departmento de Química., Centro de Investigación y de Estudios Avanzados del I. P.N., Apartado Postal 14-740

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1990年 / 47卷 / 1-2期

关键词：

Berry exchange-coordinate; dibenzobicyclic-phosphorane; X-ray-diffraction;

D O I：

10.1080/10426509008046863

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The single crystal X-ray diffraction study and the structural evaluation of l-phenyl-5-aza-2, 8-dioxa-l-phospha(V)-dibenzo[c, f]bicyclo[3, 3, 0]octane, 1 show that the compound lies on the Berry coordinate approximately 50% between a trigonal bipyramid with the oxygen atoms in axial positions and a rectangular pyramid. © 1990, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：215 / 224

页数：10

共 16 条

[1] THE SYNTHESIS, STRUCTURE, AND CHEMISTRY OF 10-PN-3 SYSTEMS - TRICOORDINATE HYPERVALENT PNICTOGEN COMPOUNDS [J].

ARDUENGO, AJ ;

STEWART, CA ;

DAVIDSON, F ;

DIXON, DA ;

BECKER, JY ;

CULLEY, SA ;

MIZEN, MB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (03) :627-647

[2]

ARESTA M, 1985, NOUV J CHIM, V9, P321

[3] CORRELATION OF RATES OF INTRAMOLECULAR TUNNELING PROCESSES, WITH APPLICATION TO SOME GROUP-V COMPOUNDS [J].

BERRY, RS .

JOURNAL OF CHEMICAL PHYSICS, 1960, 32 (03) :933-938

[4] SYNTHESIS AND REACTIVITY OF A NEW DIBENZOBICYCLIC PHOSPHORANE OF UNUSUAL HIGH STABILITY-1-PHENYL-5-AZA-2,8-DIOXA-1-PHOSPHAV-DIBENZO[C,F]BICYCLO[3.3.0]OCTANE [J].

CONTRERAS, R ;

MURILLO, A ;

URIBE, G ;

KLAEBE, A .

HETEROCYCLES, 1985, 23 (09) :2187-2192

[5]

CONTRERAS R, 1981, TETRAHEDRON LETT, P3953

[6]

FARFAN N, 1987, J ORGANOMET CHEM, V348, P149

[7] SYNTHESIS AND CRYSTAL-STRUCTURE OF A STABLE BIS(BORANE)AMINOPHOSPHANE ADDUCT - THE UNUSUALLY STRONG BASIC CHARACTER OF A NITROGEN ATOM BOUND TO PHOSPHORUS [J].

GREC, D ;

HUBERTPFALZGRAF, LG ;

RIESS, JG ;

GRAND, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (23) :7133-7134

[8] 5-COORDINATED STRUCTURES [J].

HOLMES, RR .

PROGRESS IN INORGANIC CHEMISTRY, 1984, 32 :119-235

[9] STRUCTURAL DISTORTIONS OF CYCLIC PHOSPHORANES AND BERRY EXCHANGE COORDINATE - QUANTITATIVE DESCRIPTION [J].

HOLMES, RR ;

DEITERS, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (10) :3318-3326

[10]

HOUALLA D, 1985, NOUV J CHIM, V9, P189

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