STRUCTURAL EVALUATION OF A DIBENZOBICYCLIC PHOSPHORANE - ANOTHER EXAMPLE OF A BERRY EXCHANGE COORDINATE

被引：15

作者：

CONTRERAS, R

MURILLO, A

JOSEPHNATHAN, P

机构：

[1] Departmento de Química., Centro de Investigación y de Estudios Avanzados del I. P.N., Apartado Postal 14-740

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1990年 / 47卷 / 1-2期

关键词：

Berry exchange-coordinate; dibenzobicyclic-phosphorane; X-ray-diffraction;

D O I：

10.1080/10426509008046863

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The single crystal X-ray diffraction study and the structural evaluation of l-phenyl-5-aza-2, 8-dioxa-l-phospha(V)-dibenzo[c, f]bicyclo[3, 3, 0]octane, 1 show that the compound lies on the Berry coordinate approximately 50% between a trigonal bipyramid with the oxygen atoms in axial positions and a rectangular pyramid. © 1990, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：215 / 224

页数：10

共 16 条

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LUCKENBACH R, 1973, DYNAMIC STEREOCHEMIS

[12]

March J., 1977, ADV ORGANIC CHEM, V2nd

[13]

MCEWER WE, 1975, ORGANOPHOSPHORUS S 1

[14]

MCEWER WE, 1975, ORGANOPHOSPHORUS S 2

[15] 4-MEMBERED AND 5-MEMBERED PHOSPHORUS HETEROCYCLES .20. TRICYCLIC PHOSPHORANE WITH AXIAL ANNELATION [J].

SCHMIDPETER, A ;

SCHOMBURG, D ;

SHELDRICK, WS ;

WEINMAIER, JH .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1976, 15 (12) :781-782

[16] DISTORTION OF TRIGONAL-BIPYRAMIDAL LIGAND ARRANGEMENT IN BICYCLOPHOSPHORANES - STRUCTURE OF 2,3,8,8-TETRAPHENYL[1,3,2LAMBDA5]OXAZAPHOSPHOLINO[2,3-B]BENZO[D]-[1,3,2LAMBDA5]OXAZAPHOSPHOLINE [J].

SHELDRICK, WS ;

SCHMIDPETER, A ;

WEINMAIER, JH .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1975, 14 (07) :490-491

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