A NEW ROUTE TO 3-DEOXY-D-MANNO-2-OCTULOSONIC ACID - FELKIN-ANH RULE IN RADICAL CHEMISTRY

被引：32

作者：

GIESE, B

CARBONI, B

GOBEL, T

MUHN, R

WETTERICH, F

机构：

[1] Department of Chemistry, University of Basel, CH-4056 Basel

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 19期

关键词：

CARBOHYDRATE; CO-ORGANIC COMPOUNDS; RADICALS; STEREOCHEMISTRY;

D O I：

10.1016/S0040-4039(00)79054-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ambinosyl cobalt complex 5 and silylated pyruvate 6 give under radical condition the chain elongated sugar derivative 7, a precursor of KDO (4). The intermediate radical 8 reacts stereoselectively with BrCCl3 according to the Felkin-Anh rule.

引用

页码：2673 / 2676

页数：4

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