SYNTHESIS OF ETA-3-PHOSPHAALLYL-COBALT AND ETA-3-PHOSPHAALLYL-NICKEL COMPLEXES - CRYSTAL-STRUCTURE OF [ETA-3-1-(2,4,6-TRI-TERT-BUTYLPHENYL)-1-PHOSPHAALLYL]TRICARBONYLCOBALT

被引：16

作者：

MERCIER, F

GOFF, CHL

RICARD, L

MATHEY, F

机构：

[1] Laboratoire de Chimie du Phosphore et des Métaux de Transition DCPH, Ecole Polytechnique

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 389卷 / 03期

关键词：

D O I：

10.1016/0022-328X(90)85433-Y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first (η3-1-phosphaallyl)tricarbonylcobalt complex has been obtained by reaction of a (supermesityl)(vinyl)halophosphine with Co2(CO)8 at room temperature, and its structure established by X-ray diffraction study. The reaction of (mesityl)(propenyl)phosphine with nickelocene and allyl iodide gives the corresponding CpNi(I)(R2PH) complex, which, upon treatment with DABCO, gives a complex in which the phosphaallyl group is η3-ligated to CpNi and η1-P-ligated to CpNi(I). © 1990.

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页码：389 / 397

页数：9

相关论文

共 16 条

[1] LOWER COORDINATED PHOSPHORUS-COMPOUNDS .38. TRICARBONYL(1,3-DIPHOSPHAALLYL)COBALT, A PHOSPHORUS ANALOG OF (ETA-3-ALLYL)TRICARBONYLCOBALT [J].

APPEL, R ;

SCHUHN, W ;

KNOCH, F .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1985, 24 (05) :420-421

[2] LOWLY-COORDINATED PHOSPHORUS-COMPOUNDS .53. 1,3-DIPHOSPHAALLYL-NICKEL COMPLEXES [J].

APPEL, R ;

SCHUHN, W ;

KNOCH, F .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 319 (03) :345-350

[3] DIMERIZATION OF PROPYLENE WITH CATALYSTS EXHIBITING ACTIVITIES LIKE HIGHLY-ACTIVE ENZYMES [J].

BOGDANOVIC, B ;

SPLIETHOFF, B ;

WILKE, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1980, 19 (08) :622-623

[4] SYNTHESIS AND CRYSTAL-STRUCTURE OF ETA-3-PHOSPHAALLYL-MOLYBDENUM AND ETA-3-PHOSPHAALLYL-TUNGSTEN COMPLEXES [J].

HUGELLEGOFF, C ;

MERCIER, F ;

RICARD, L ;

MATHEY, F .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 363 (03) :325-333

[5] MAIN GROUP ELEMENT-TRANSITION METAL MULTIPLE BONDS .7. SYNTHESIS, STRUCTURE, AND ADDITION-REACTIONS OF [CP(CO)2W=PIPR2], [CP(CO)2W=PTERT-BU2] [J].

JORG, K ;

MALISCH, W ;

REICH, W ;

MEYER, A ;

SCHUBERT, U .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (01) :92-93

[6]

MATHEY F, 1987, NEW J CHEM, V11, P585

[7] REDUCTION COMPLEXATION OF PHOSPHINE SULFIDES BY NICKELOCENE [J].

MATHEY, F .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 87 (03) :371-377

[8] EQUILIBRIUM BETWEEN (ETA-1-PHOSPHAALLYL)TUNGSTEN AND (ETA-3-PHOSPHAALLYL)TUNGSTEN COMPLEXES [J].

MERCIER, F ;

MATHEY, F .

ORGANOMETALLICS, 1990, 9 (03) :863-864

[9] ETA-3-1-PHOSPHAALLYLIRON COMPLEXES WITH ADDITIONAL W(CO)5-COORDINATION AT THE PHOSPHORUS - THE 1-PHOSPHAALLYL LIGAND AS 5E-DONOR [J].

MERCIER, F ;

FISCHER, J ;

MATHEY, F .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (04) :357-359

[10] THERMAL-ISOMERIZATION OF A SECONDARY VINYLPHOSPHINE INTO A PHOSPHAALKENE [J].

MERCIER, F ;

HUGELLEGOFF, C ;

MATHEY, F .

TETRAHEDRON LETTERS, 1989, 30 (18) :2397-2398