NUCLEOPHILIC-SUBSTITUTION OF TETRACARBONYLIRON COMPLEXES OF GAMMA-ACETOXYCROTONATES - THE HOMOLOGOUS MICHAEL REACTION

被引：33

作者：

GREEN, JR

CARROLL, MK

机构：

[1] Department of Chemistry, Biochemistry University of Windsor, Windsor

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 09期

关键词：

D O I：

10.1016/S0040-4039(00)92028-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Iron tetracarbonyl complexes of gamma-acetoxy-alpha,beta-unsaturated esters react with silyl enol in the presence of boron trifluoride-etherate to give substitution in the gamma-position. The results are interpreted as being indicative of the intermediacy of a tetracarbonyliron-allyl cation complex which reacts at the terminus remote from the ester function.

引用

页码：1141 / 1144

页数：4

共 36 条

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