STEREOSELECTIVE STEPWISE REDUCTION OF COORDINATED ACETONITRILE WITH CHIRAL TP'(CO)(RCCR')W+ TEMPLATES

被引：67

作者：

FENG, SG ^{[1
]}

TEMPLETON, JL ^{[1
]}

机构：

[1] UNIV N CAROLINA,DEPT CHEM,WR KENAN JR LABS,CHAPEL HILL,NC 27599

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 03期

关键词：

D O I：

10.1021/om00039a039

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Stepwise reduction of the acetonitrile ligand in [Tp'(CO)(RC = CR')W(N = CMe)][BF4] has been accomplished with sequential addition of nucleophiles and electrophiles to the carbon-nitrogen triple bond. Intermediate metal complexes containing coordinated azavinylidene, imine, amide, and amine nitrogen donor ligands have been isolated and characterized. Nucleophilic addition to the imine complexes is highly stereoselective. Acidification of the amine complex in acetonitrile forms the free ammonium salt, and solvent coordination regenerates the acetonitrile adduct.

引用

页码：1295 / 1303

页数：9

共 45 条

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