ELECTROCHEMICAL SYNTHESIS OF METAL(II) COMPLEXES OF SCHIFF-BASES - THE CRYSTAL-STRUCTURE OF ACETONITRILE-BIS(2-[(2-PYRROLE)METHYLIMINO]-4,6-DIMETHYLPHENOLATO(ZINC(II)

被引：37

作者：

CASTRO, JA

ROMERO, J

GARCIAVAZQUEZ, JA

MACIAS, A

SOUSA, A

机构：

[1] UNIV SANTIAGO,DEPT QUIM INORGAN,SANTIAGO,SPAIN

[2] RHEIN WESTFAL TH AACHEN,INST ANORGAN CHEM,W-5100 AACHEN,GERMANY

来源：

POLYHEDRON | 1993年 / 12卷 / 11期

关键词：

D O I：

10.1016/S0277-5387(00)84331-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The electrochemical oxidation of anodic metals (Co, Ni, Cu, Zn and Cd) in acetonitrile solution containing a Schiff base (H-2L) derived from H-pyrrole-2-carbaldehyde and a substituted o-aminophenol yielded the complexes M(HL)2 and acetonitrile-bis{2-[(2-pyrrole)methyliminol-4,6-dimethylphenolato}zinc(II). X-ray data show the latter to have a distorted bipyramidal coordination polyhedron that does not include the pyrrole nitrogen atoms.

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页码：1391 / 1397

页数：7

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