THE B(1A')]-X(1A') SPECTRUM OF CIFCS

被引：5

作者：

CLOUTHIER, DJ ^{[1
]}

KNIGHT, AR ^{[1
]}

STEER, RP ^{[1
]}

JUDGE, RH ^{[1
]}

MOULE, DC ^{[1
]}

机构：

[1] BROCK UNIV,DEPT CHEM,ST CATHARINES L2S 3A1,ONTARIO,CANADA

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1980年 / 83卷 / 01期

关键词：

Chemical bonds - Ground state;

D O I：

10.1016/0022-2852(80)90317-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The vibrational structure of the first strong electronic transition, B¯1A′ → X¯1A′, of CIFCS has been analyzed. Four excited state frequencies have been identified. The excited state is nonplanar and has a barrier to inversion of 5=2000 cm-1 and a C-S bond which is about 0.5 Å longer than the ground state. Copyright © 1980 by Academic Press, Inc.

引用

页码：148 / 160

页数：13