NONLINEAR OPTICAL STUDIES OF NICKEL DITHIOLENE COMPLEXES

被引：82

作者：

WINTER, CS ^{[1
]}

OLIVER, SN ^{[1
]}

MANNING, RJ ^{[1
]}

RUSH, JD ^{[1
]}

HILL, CAS ^{[1
]}

UNDERHILL, AE ^{[1
]}

机构：

[1] UNIV COLL N WALES,DEPT CHEM,BANGOR LL57 2UW,GWYNEDD,WALES

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1992年 / 2卷 / 04期

关键词：

NICKEL DITHIOLENE; NONLINEAR OPTICAL MATERIAL; REFRACTIVE INDEX; 2-PHOTON ABSORPTION; DEGENERATE 4-WAVE MIXING;

D O I：

10.1039/jm9920200443

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The third-order optical non-linearity, chi(3), linear absorption coefficient, alpha, and the ratio of the real to imaginary parts of chi(3) have been measured at 1.06-mu-m for a range of nickel dithiolene complexes with absorption bands between 0.77 and 1.06-mu-m. From these data the non-linear refractive index, n2, and the device-based figure of merit, W (= DELTA-n(sat)/alpha-lambda), were calculated. W was found to exceed 2 for materials with absorption maxima below 0.8-0.85-mu-m. The non-linear refractive index of a poly(methyl methacrylate) host doped with 8 x 10(19) molecules cm-3 of a nickel dithiolene was also measured and found to be nearly 2 x 10(-9) cm2 KW-1.

引用

页码：443 / 447

页数：5

共 21 条

[1] INTENSITY DEPENDENT INDEX OF REFRACTION IN ORGANIC MATERIALS [J].

CARTER, GM ;

CHEN, YJ ;

TRIPATHY, SK .

OPTICAL ENGINEERING, 1985, 24 (04) :609-612

[2]

COTTER D, 1990, IQEC, V8, pQPD33

[3] DIAGRAMMATICAL ANALYSIS OF PHASE CONJUGATION USING 4-WAVE AND 3-WAVE MIXING PROCESSES IN KERR-LIKE NONSATURATED MEDIA [J].

GOWER, MC .

IEEE JOURNAL OF QUANTUM ELECTRONICS, 1985, 21 (03) :182-187

[4] FEMTOSECOND MEASUREMENTS OF THE NONRESONANT NONLINEAR INDEX IN ALGAAS [J].

LAGASSE, MJ ;

ANDERSON, KK ;

WANG, CA ;

HAUS, HA ;

FUJIMOTO, JG .

APPLIED PHYSICS LETTERS, 1990, 56 (05) :417-419

[5] RESONANT 3RD-ORDER HYPERPOLARIZABILITIES OF LARGE ORGANIC-MOLECULES [J].

MALONEY, C ;

BLAU, W .

JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1987, 4 (06) :1035-1039

[6]

McCleverty J. A., 1968, PROG INORG CHEM, V10, P49, DOI DOI 10.1002/9780470166116.CH2

[7] 2-PHOTON ABSORPTION AS A LIMITATION TO ALL-OPTICAL SWITCHING [J].

MIZRAHI, V ;

DELONG, KW ;

STEGEMAN, GI ;

SAIFI, MA ;

ANDREJCO, MJ .

OPTICS LETTERS, 1989, 14 (20) :1140-1142

[8] MESOMORPHIC TRANSITION-METAL COMPLEXES .4. DITHIENE COMPLEXES OF NI, PD, AND PT [J].

MUELLERWESTERHOFF, UT ;

NAZZAL, A ;

COX, RJ ;

GIROUD, AM .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1980, 56 (08) :249-255

[9]

OLIVER SN, 1990, SPIE P, V1337, P81

[10]

PEPPER DM, 1983, OPTICAL PHASE CONJUG, P24

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