A NOVEL REARRANGEMENT OF TERTIARY ALPHA-ALLENIC ALCOHOL CARBAMATES - PREPARATION OF 2-O-CARBAMOYL-4,4-DISUBSTITUTED-1,3-BUTADIENES

被引：8

作者：

FRIESEN, RW

KOLACZEWSKA, AE

KHAZANOVICH, N

机构：

[1] Department of Chemistry, University of Toronto, Lash Miller Chemical Laboratories, Toronto, Ont. M5S 1A1

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 45期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/S0040-4039(00)61758-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of a variety of tertiary alpha-allenic alcohols with N-tosyl isocyanate results in a facile and novel rearrangement reaction that provides isolable 2-O-carbamoyl-4,4-disubstituted-1,3-butadienes in a stereoselective manner.

引用

页码：6715 / 6718

页数：4

共 10 条

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