ORIENTATIONAL SELECTIVITY FOR THE INCLUSION OF ACETONITRILE IN TAILOR-MADE MACROBICYCLIC HOST MOLECULES

被引：19

作者：

BERSCHEID, R

NIEGER, M

VOGTLE, F

机构：

[1] UNIV BONN,INST ORGAN CHEM & BIOCHEM,GERHARD DOMAGK STR 1,W-5300 BONN 1,GERMANY

[2] UNIV BONN,INST ANORGAN CHEM,W-5300 BONN 1,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 19期

关键词：

D O I：

10.1039/c39910001364

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first sigma-pi-interaction between a C-H acidic acetonitrile methyl group and a 'pi-basic' host cavity is described based on the X-ray structure of the complex between the host 3 and MeCN; comparison with the structure of the complex between 1 and MeCN shows orientational selectivity for MeCN in the two hosts.

引用

页码：1364 / 1366

页数：3

共 6 条

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