INCLUSION OF ACETONITRILE IN A MACROBICYCLIC HOST MOLECULE

被引：18

作者：

VOGTLE, F ^{[1
]}

BERSCHEID, R ^{[1
]}

SCHNICK, W ^{[1
]}

机构：

[1] UNIV BONN,INST ANORGAN CHEM,W-5300 BONN 1,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 06期

关键词：

D O I：

10.1039/c39910000414

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first inclusion complex of acetonitrile in a molecular cavity is described; X-ray structure and IR spectra show that the pi-donor host 4 encloses acetonitrile as a pi-acceptor selectively inside its molecular cavity, whereas empty intermolecular cavities are not occupied by acetonitrile.

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页码：414 / 416

页数：3

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