METHYL-3-OXO-OMEGA-FLUOROSULFONYLPERFLUOROPENTANOATE - A VERSATILE TRIFLUOROMETHYLATING AGENT FOR ORGANIC HALIDES

被引：66

作者：

CHEN, QY

DUAN, JX

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 18期

关键词：

D O I：

10.1039/c39930001389

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Methyl 3-oxo-omega-fluorosulfonylperfluoropentanoate FSO2CF2CF2OCF2CO2Me 1, prepared through the reaction of readily available ICF2CF2OCF2CF2SO2F and SO3 followed by MeOH, is a very convenient trifluoromethylating agent; in the presence of copper(I) iodide, 1 not only reacts with vinyl, benzyl allyl, phenyl iodides and bromides, but also with aryl chlorides to give the corresponding trifluoromethyl compounds in moderate to high yield; a probable reaction mechanism is proposed.

引用

页码：1389 / 1391

页数：3

共 31 条

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