A NEW METHOD FOR THE SYNTHESIS OF HETEROMETALLIC COMPLEXES - SYNTHESES AND STRUCTURES OF [(PHCH(2)CH(2)NLI)(3)SB(THF)](2) AND [SB-3(CYN)(4)(NME(2))(2)]LI

被引：55

作者：

EDWARDS, AJ ^{[1
]}

PAVER, MA ^{[1
]}

RAITHBY, PR ^{[1
]}

RENNIE, MA ^{[1
]}

RUSSELL, CA ^{[1
]}

WRIGHT, DS ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 12期

关键词：

D O I：

10.1002/anie.199412771

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Successive metalation of primary amines, first with nBuLi and then with Sb(NMe2)3, has enabled the preparation of the heterometallic complexes 1 and 2. Neutra [Ph(CH2)2N(H)Li]n and ionic Li[Sb(cyNH)4] occur as the intermediates in the formation of 1 and 2, respectively. (Formula Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1277 / 1279

页数：3

共 26 条

[11] PREPARATION OF SOME TRIS(DIAKYLAMINO)STIBINES AND THEIR PROPERTIES [J].