FUNCTIONALIZATION OF C-60 BUCKMINSTERFULLERENE BY [8+2] CYCLOADDITION - SPECTROSCOPIC AND ELECTRON-TRANSFER PROPERTIES OF A TETRAHYDROAZULENOFULLERENE

被引：39

作者：

BEER, E ^{[1
]}

FEUERER, M ^{[1
]}

KNORR, A ^{[1
]}

MIRLACH, A ^{[1
]}

DAUB, J ^{[1
]}

机构：

[1] UNIV REGENSBURG,INST ORGAN CHEM,D-93040 REGENSBURG,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 10期

关键词：

D O I：

10.1002/anie.199410871

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The novel C60 cycloadduct 1 is formed in the reaction of 8‐methoxyheptafulvene with buckminster‐fullerene C60. Compound 1 can be reduced to its tetraanion in four reversible steps; the spectral properties of the radical anion, dianion, and trianion were examined by UV/VIS/NIR spectroelectro‐chemistry. Adduct 1 may lead to other functional‐ized fullerenes having substructures with electron‐transfer properties. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1087 / 1089

页数：3