TRANSIENT-BEHAVIOR AT PLANAR MICROELECTRODES - DIFFUSION CURRENT AT RING ELECTRODES BY THE INTEGRAL-EQUATION METHOD

被引:40
作者
COPE, DK
SCOTT, CH
TALLMAN, DE
机构
[1] N DAKOTA STATE UNIV,DEPT CHEM,FARGO,ND 58105
[2] N DAKOTA STATE UNIV,DEPT MATH,FARGO,ND 58105
来源
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1990年 / 285卷 / 1-2期
关键词
Electric Measurements--Current - Electrodes; Electrochemical - Mathematical Techniques--Integral Equations;
D O I
10.1016/0022-0728(90)87108-V
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The transient diffusion-limited current at the ring electrode is calculated by the integral equation method over significant time intervals (to steady state or near steady state) for the full range of significant ring sizes. We also report on the development of generic programs for the integral equation method which will aid in the implementation of this method by others working in this area. The results of this paper were obtained by the application of these programs to the ring electrode kernel. © 1990.
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页码:49 / 69
页数:21
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