A NEW SYNTHESIS OF AMINE- AND PHOSPHINE-BORANES

被引：55

作者：

NAINAN, KC

RYSCHKEW.GE

机构：

[1] Department of Chemistry, University of Florida, Gainesville

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 12期

关键词：

D O I：

10.1021/ic50082a027

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new, rapid, and high-yield synthesis of borane adducts with amines and phosphines has been developed. It is based on the reaction of sodium borohydride and iodine in the presence of the donor. The procedure is applicable to adducts of ammonia, primary, secondary, and tertiary amines, di- and triamines, pyridines, triphenylphosphine, and diphosphines. The following new compounds have been prepared: 2-methoxypyridine-borane, 2,2′-dipyridyl-bis(borane), bis(diphenylphosphino) methane-bis(borane), and 1,2-bis(diphenylphosphino)ethane-bis(borane). © 1969, American Chemical Society. All rights reserved.

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页码：2671 / &

相关论文

共 25 条

[1] NEW AND CONVENIENT ROUTE TO AMINE-BORANES [J].

ASHBY, EC ;

FOSTER, WE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (17) :3407-&

[2]

BACKER EB, 1955, J CHEM PHYS, V23, P1981

[3] BORANE EXCHANGE REACTIONS [J].

BALDWIN, RA ;

WASHBURN, RM .

JOURNAL OF ORGANIC CHEMISTRY, 1961, 26 (09) :3549-&

[4] NUCLEAR MAGNETIC RESONANCE SPECTRA OF PYRIDINE AND SOME DEUTERATED AND METHYLATED PYRIDINES [J].

BERNSTEIN, HJ ;

SCHNEIDER, WG .

JOURNAL OF CHEMICAL PHYSICS, 1956, 24 (02) :469-470

[5]

BREY WS, 1964, ADVANCES CHEMISTRY S, P100

[6] PROTON MAGNETIC RESONANCE SPECTRA OF SOME ORGANODIPHOSPHORUS COMPOUNDS [J].

BROPHY, JJ ;

GALLAGHE.MJ .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1967, 20 (03) :503-&

[7] Studies in stereochemistry I Steric strains as a factor in the relative stability of some coordination compounds of boron [J].

Brown, HC ;

Schlesinger, HI ;

Cardon, SZ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1942, 64 :325-329

[8] N.M.R. SPECTRA OF SUBSTITUTED DIPHOSPHINES AND THEIR DERIVATIVES . DECEPTIVELY SIMPLE SPECTRA [J].

CARTY, AJ ;

HARRIS, RK .

CHEMICAL COMMUNICATIONS, 1967, (05) :234-&

[9] BISAMINE COMPLEXES OF BORONIUM IONS . REACTION OF AMINE BORANES WITH IODINE [J].

DOUGLASS, JE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (24) :5431-&

[10] BONDING AND REACTIVITY IN TRIPHENYLPHOSPHINEBORANE [J].

FRISCH, MA ;

HEAL, HG ;

MACKLE, H ;

MADDEN, IO .

JOURNAL OF THE CHEMICAL SOCIETY, 1965, (FEB) :899-&