A NEW SYNTHESIS OF AMINE- AND PHOSPHINE-BORANES

被引：55

作者：

NAINAN, KC

RYSCHKEW.GE

机构：

[1] Department of Chemistry, University of Florida, Gainesville

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 12期

关键词：

D O I：

10.1021/ic50082a027

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new, rapid, and high-yield synthesis of borane adducts with amines and phosphines has been developed. It is based on the reaction of sodium borohydride and iodine in the presence of the donor. The procedure is applicable to adducts of ammonia, primary, secondary, and tertiary amines, di- and triamines, pyridines, triphenylphosphine, and diphosphines. The following new compounds have been prepared: 2-methoxypyridine-borane, 2,2′-dipyridyl-bis(borane), bis(diphenylphosphino) methane-bis(borane), and 1,2-bis(diphenylphosphino)ethane-bis(borane). © 1969, American Chemical Society. All rights reserved.

引用

页码：2671 / &

共 25 条

[21] BIS (PYRIDINE) BORONIUM SALTS - SYNTHESES AND FORMATION KINETICS [J].