PREPARATION AND CHARACTERIZATION OF HALO(DIETHYLDITHIOCARBAMATO) (TRIETHYLPHOSPHINE)NICKEL(II) COMPLEXES

被引：2

作者：

DANESHI, M

BLUHM, T

机构：

[1] UNIV HAMBURG,INST ANORGAN & ANGEW CHEM,D-2000 HAMBURG 13,FED REP GER

[2] UNIV DUSSELDORF,INST PHYS CHEM,D-4000 DUSSELDORF 1,FED REP GER

来源：

MONATSHEFTE FUR CHEMIE | 1979年 / 110卷 / 06期

关键词：

Conductivity measurements; Ni(II); complexes; halogeno(diethyldithiocarbamato) (triethylphosphin); Susceptibility measurements;

D O I：

10.1007/BF00938292

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complexes [Ni(P Et3)2dtc]X (1) and Ni(P Et3)Xdtc (2) (dtc=S2CN Et2, X=Cl, Br, I) have been prepared. As conductivity, susceptibility, UV and IR measurements show, the cations [Ni(P Et3)2dtc]+ of 1 and the complexes 2 at ambient temperature have square-planar structure. We suppose there might exist an equilibrium for 2 between square-planar and tetrahedral configuration. © 1979 Springer-Verlag.

引用

页码：1357 / 1366

页数：10

共 29 条

[21] STEREOCHEMISTRY OF 5-COORDINATE NICKEL(II) AND COBALT(II) COMPLEXES [J].