THE ASYMMETRIC METALATION OF CHIRAL ARYLALDEHYDE ACETAL CHROMIUM TRICARBONYL COMPLEXES

被引:45
作者
KONDO, Y [1 ]
GREEN, JR [1 ]
HO, JW [1 ]
机构
[1] UNIV WINDSOR,DEPT CHEM & BIOCHEM,WINDSOR N9B 3P4,ONTARIO,CANADA
关键词
D O I
10.1021/jo00026a005
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The chiral chromium tricarbonyl complex of benzaldehyde acetal 2, derived from (+)-diethyl tartrate, can be metalated by n-BuLi and subsequently functionalized by various electrophiles with a minimum of 86% de.
引用
收藏
页码:7199 / 7201
页数:3
相关论文
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