UNSYMMETRICALLY DISUBSTITUTED FERROCENES .8. SYNTHESIS AND REACTIVITY OF SOME 2-SUBSTITUTED FERROCENYLPHOSPHINES

被引:56
作者
MARR, G
HUNT, T
机构
[1] Department of Applied Science, Wolverhampton College of Technology
来源
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 07期
关键词
D O I
10.1039/j39690001070
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The reaction of lithiated (dimethylaminomethyl)ferrocene with chlorodiphenylphosphine gave 2-(dimethylamino-methyl)ferrocenyldiphenylphospnine. This phosphinoferrocene has been converted into a variety of 1,2-disubstituted and 1,2,3-trisubstituted ferrocenes. Chlorodiphenylphosphine has been condensed with 1,1′-dilithioferrocene to give 1,1′-bisdiphenylphosphinoferrocene.
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页码:1070 / &
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