THE INFRARED-LASER SPECTRUM OF THE UPSILON-3-BAND OF OCS+

被引:5
作者
FEHER, M
SALUD, C
ROSSLEIN, M
MAIER, JP
机构
[1] Institut für Physikalische Chemie, Universität Basel, CH-4056 Basel
关键词
D O I
10.1016/0022-2852(90)90286-Y
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
The rotationally resolved ν3 band in the infrared spectrum of OCS+ was recorded. Two rotational series were found in the 2015-2085 cm-1 range; one is assigned to the ν3 fundamental transition within the 2Π 1 2 component of the ground electronic state of OCS+, the other is tentatively assigned to a vibrational hot band. The determined constants of OCS+ (X2Π 1 2) are B″0 = 0.201149(12) cm-1, ν0 = 2038.98413(20) cm-1. © 1990.
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页码:167 / 174
页数:8
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