NOVEL TYPES OF HYDROGEN-BONDS INVOLVING TRANSITION-METAL ATOMS AND PROTON-TRANSFER (XH...M, [MH]+...B, [MH]+...A-)

被引：33

作者：

EPSTEIN, LM

KRYLOV, AN

SHUBINA, ES

机构：

[1] A.N. Nesmeyanov Institute of Organo-element Compounds, the Russian Academy of Science, Moscow, Vavilov str. 28

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1994年 / 322卷

关键词：

D O I：

10.1016/0022-2860(94)87052-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The conditions governing the formation of hydrogen bonding involving transition metal atoms of the molecular, ion molecular and ionic types in low polar media were found. IR and UV-Vis spectral characteristics of these bonds were determined. Similarities between the spectral properties of hydrogen bonds with a metal atom and with common organic bases as well as some particular characteristics of the former were established. The equilibrium between molecular (OH...M) and ionic (O-...[HM]-) hydrogen-bonded complexes was investigated.

引用

页码：345 / 352

页数：8

共 27 条

[1] ALEXANYAN VG, 1980, ZH FIZ KHIM, V54, P663
[2] CHERICHELLI G, 1977, J ORGANOMET CHEM, V127, P357
[3] INVESTIGATION OF B - HA REVERSIBLE B+H - A-EQUILIBRIUM IN COMPLEXES OF TRIFLUOROACETIC-ACID WITH PYRIDINES I DICHLOROMETHANE BY 2ND DERIVATIVE INFRARED-SPECTROSCOPY
DEGASZAFRAN, Z
GRUNDWALDWYSPIANSKA, M
SZAFRAN, M
[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1991, 47 (05): : 543 - 550
[4] HYDROGEN-BOND AND PROTON-TRANSFER IN COMPLEXES OF TRIOCTYLAMINE WITH HALOGENOACETIC ACIDS
DENISOV, GS
GUSAKOVA, GV
SMOLYANSKY, AL
[J]. JOURNAL OF MOLECULAR STRUCTURE, 1973, 15 (03) : 377 - 382
[5] IONIC HYDROGEN-BOND AND DEPROTONATION OF CATIONIC HYDRIDE [(ETA-5-C5ME5)2OSH]+A-
EPSTEIN, LM
SHUBINA, ES
KRYLOV, AN
KREINDLIN, AZ
RYBINSKAYA, MI
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 460 (01) : 87 - 89
[6] INTERACTION BETWEEN [(ETA(5)-C5ME5)2OSH]+PF6- AND NITROGEN OR OXYGEN BASES - HYDROGEN-BONDS OF THE TYPE [OSH]+ ... B
EPSTEIN, LM
SHUBINA, ES
KRYLOV, AN
KREINDLIN, AZ
RYBINSKAYA, MI
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 447 (02) : 277 - 280
[7] EPSTEIN LM, 1992, METALLOORG KHIM, V5, P61
[8] EPSTEIN LM, 1992, KHIM PHYS, V11, P755
[9] EPSTEIN LM, 1970, DOKL AKAD NAUK SSSR, V190, P128
[10] Golubev N. S., 1981, HYDROGEN BOND, P212

← 1 2 3 →