POLYSILANE SYNTHESIS BY CATALYTIC DISPROPORTIONATION OF ALKOXYDISILANES WITH ORGANOLITHIUM REAGENTS

被引：4

作者：

KABETA, K ^{[1
]}

WAKAMATSU, S ^{[1
]}

IMAI, T ^{[1
]}

机构：

[1] TOSHIBA SILICONE CO LTD, CTR RES & DEV, GUNMA 373, JAPAN

来源：

CHEMISTRY LETTERS | 1995年 / 02期

关键词：

D O I：

10.1246/cl.1995.119

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Network polysilanes with various substituents have been prepared by a disproportionation reaction of 1,1,2,2-tetraethoxy-1,2-dimethyldisilane with a small amount of organolithium reagents. Aromatic dilithio compounds lead to incorporation of aromatic bridges into the network polysilanes, which show relatively higher electroconductivity by iodine doping. It seems that lithium ethoxide catalyzes the polymerization.

引用

页码：119 / 120

页数：2

共 10 条

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