TRANSMISSION MOSSBAUER AND FTIR SPECTROSCOPIC STUDIES OF BINARY NICKEL(II)-IRON(III) HYDROXIDE SYSTEMS

被引：10

作者：

KAMNEV, AA

RISTIC, M

ANGELOV, V

机构：

[1] RUDJER BOSKOVIC INST,ZAGREB 41001,CROATIA

[2] UNIV SOFIA,DEPT ATOM PHYS,BU-1126 SOFIA,BULGARIA

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1995年 / 349卷

关键词：

D O I：

10.1016/0022-2860(95)08713-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Transmission Mossbauer and Fourier transform infrared spectroscopic data obtained for binary nickel(II)-iron(III) hydroxide systems in a broad range of compositions (3 to 60 at. % Fe/(Ni+Fe)) are compared. Structural transformations of the samples and their surface layers are considered, depending on their bulk gross compositions. The formation of a nickel ferrite precursor is shown to be promoted in the crystallites surface layers even at much lower gross Fe-to-Ni ratios than that in NiFe2O4 owing to surface enrichment with iron, as confirmed by Auger electron spectroscopic analyses.

引用

页码：77 / 80

页数：4