FEMTOSECOND TEMPORAL SPECTROSCOPY OF ICL - INVERSION TO THE A 3-PI-1 STATE POTENTIAL

被引:37
作者
JANSSEN, MHM
BOWMAN, RM
ZEWAIL, AH
机构
[1] Arthur Amos Noyes Laboratory of Chemical Physics2 2 Contribution No. 8157., California Institute of Technology, Pasadena
关键词
D O I
10.1016/0009-2614(90)87280-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The femtosecond evolution of the wave packet is probed for ICI on the A 3Π1 potential surface. Vibrational transients for v′ = 9-28 have been obtained by varying the wavelength of the pump pulse. The periods of the wave packet motion are used to invert to the potential ΔR (V). Both the RKR and a modified classical inversion method are applied and the advantages of both methods are discussed. © 1990.
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页码:99 / 108
页数:10
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