NEW STABLE GERMENES

被引:32
作者
LAZRAQ, M
COURET, C
ESCUDIE, J
SATGE, J
SOUFIAOUI, M
机构
[1] UNIV TOULOUSE 3,URA 477,CHIM ORGANOMINERAUX LAB,118 ROUTE NARBONNE,F-31062 TOULOUSE,FRANCE
[2] UNIV MOHAMMED 5,FAC SCI,DEPT CHIM,CYCLOADDIT LAB,RABAT,MOROCCO
关键词
D O I
10.1016/S0277-5387(00)86091-X
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two new stable fluorenylidene germenes 5 and 6 substituted on germanium with two bulky bisyls [(Me3Si)2CH] or with a bisyl and a mesityl group have been synthesized by dehydrofluorination of the corresponding fluorogermanes by tert-butyllithium. The ditert-butylfluorenylidene germene 7 could not be obtained by this route, but its lithio precursor 8 can be used as its synthetic equivalent.
引用
收藏
页码:1153 / 1161
页数:9
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