NEW STABLE GERMENES

被引：32

作者：

LAZRAQ, M

COURET, C

ESCUDIE, J

SATGE, J

SOUFIAOUI, M

机构：

[1] UNIV TOULOUSE 3,URA 477,CHIM ORGANOMINERAUX LAB,118 ROUTE NARBONNE,F-31062 TOULOUSE,FRANCE

[2] UNIV MOHAMMED 5,FAC SCI,DEPT CHIM,CYCLOADDIT LAB,RABAT,MOROCCO

来源：

POLYHEDRON | 1991年 / 10卷 / 11期

关键词：

D O I：

10.1016/S0277-5387(00)86091-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new stable fluorenylidene germenes 5 and 6 substituted on germanium with two bulky bisyls [(Me3Si)2CH] or with a bisyl and a mesityl group have been synthesized by dehydrofluorination of the corresponding fluorogermanes by tert-butyllithium. The ditert-butylfluorenylidene germene 7 could not be obtained by this route, but its lithio precursor 8 can be used as its synthetic equivalent.

引用

收藏

页码：1153 / 1161

页数：9

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