MAGNETIC-SUSCEPTIBILITY AND ELECTRON-PARAMAGNETIC RESONANCE-SPECTRUM OF TETRAVALENT PRASEODYMIUM IONS IN BAPRO3

被引：30

作者：

HINATSU, Y

机构：

[1] Department of Chemistry, Japan Atomic Energy Research Institute, Tokai-mura, Ibaraki

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1993年 / 102卷 / 02期

关键词：

D O I：

10.1006/jssc.1993.1046

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tetravalent praseodymium perovskite, BaPrO3, was prepared, and its magnetic susceptibility was measured in the temperature range between 4.2 K and room temperature. Magnetic ordering was found at 11.5 K. A very sharp decline of the susceptibility was observed when the temperature was increased through this transition temperature. Magnetic susceptibilities of BaPr1-yCeyO3 solid solutions were also measured. Electron paramagnetic resonance (EPR) spectra could be measured only at 4.2 K for the sample of praseodymium ion doped in diamagnetic BaCeO3. The spectra were complicated. The results of magnetic measurements show that the praseodymium ion is in the tetravalent state. © 1993 Academic Press. All rights reserved.

引用

页码：362 / 367

页数：6

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