ORGANOLEAD(IV) TRICARBOXYLATES, NEW REAGENTS FOR ORGANIC-SYNTHESIS - INVITED REVIEW

被引：90

作者：

PINHEY, JT

机构：

[1] Department of Organic Chemistry, University of Sydney

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1991年 / 44卷 / 10期

关键词：

D O I：

10.1071/CH9911353

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aryl-, vinyl- and alk-1-ynyl-lead(IV) tricarboxylates act as electrophilic arylating, vinylating and alkynylating agents, respectively, with a variety of nucleophiles, especially soft carbon nucleophiles such as beta-dicarbonyl compounds, phenols and nitroalkanes. In their reactions, they show a marked preference for carbon-carbon bond formation, especially in which a quaternary centre is produced. The formation and the synthetically useful reactions of these new reagents are reviewed.

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页码：1353 / 1382

页数：30

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