REGIOSELECTIVE AND ENANTIOSELECTIVE HYDROSILYLATION OF 1-ARYLALKENES BY USE OF PALLADIUM-MOP CATALYST

被引：56

作者：

UOZUMI, Y

KITAYAMA, K

HAYASHI, T

机构：

[1] HOKKAIDO UNIV,CATALYSIS RES CTR,SAPPORO,HOKKAIDO 060,JAPAN

[2] HOKKAIDO UNIV,GRAD SCH PHARMACEUT SCI,SAPPORO,HOKKAIDO 060,JAPAN

来源：

TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 12期

关键词：

D O I：

10.1016/S0957-4166(00)82214-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrosilylation of styrenes bearing beta-substituents with trichlorosilane was catalyzed by a palladium complex (0.1 mol %) coordinated with (R)-2-methoxy-2'-diphenylphosphino-1,1'-binaphthyl ((R)-MeO-MOP) to give high yields of optically active 1-aryl-1-silylalkanes (80 similar to 85% ee) as single regioisomers. The resulting silanes were readily converted into the corresponding optically active alcohols (80 similar to 99% yield).

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页码：2419 / 2422

页数：4

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