OBSERVATION OF DIFLUORINATED HIGHER FULLERENE ANIONS BY KNUDSEN CELL MASS-SPECTROMETRY AND DETERMINATION OF ELECTRON-AFFINITIES OF C60F2 AND C70F2

被引：34

作者：

BOLTALINA, OV

SIDOROV, LN

SUKHANOVA, EV

SOROKIN, ID

机构：

[1] Department of Chemistry, Moscow State University, Moscow

来源：

CHEMICAL PHYSICS LETTERS | 1994年 / 230卷 / 06期

关键词：

D O I：

10.1016/0009-2614(94)01204-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Difluorinated higher fullerenes have been studied by Knudsen cell mass spectrometry. Thermal negative ions CnF2-, (n = 60, 70, 72, 74, 76 and 78) were produced inside the effusion cell as well as the neutral molecules C60F2 and C70F2. From the equilibrium constants for the electron exchange reactions between difluorinated fullerenes and their parents electron affinity values were derived for C60F2 (2.74 eV) and C70F2 (2.80 eV).

引用

页码：567 / 570

页数：4

共 17 条

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