SYNTHESIS AND STRUCTURE OF A VESICULAR ASSEMBLY OF DIALKYLAMMONIUM-TYPE AMPHIPHILE CARRYING L-3-(3-N-ETHYLCARBAZOLYL)ALANINE

被引：12

作者：

TAKU, K ^{[1
]}

SASAKI, H ^{[1
]}

KIMURA, S ^{[1
]}

IMANISHI, Y ^{[1
]}

机构：

[1] KYOTO UNIV,DEPT POLYMER CHEM,SAKYO KU,KYOTO 60601,JAPAN

来源：

AMINO ACIDS | 1994年 / 7卷 / 03期

关键词：

AMINO ACIDS; UNNATURAL AMINO ACID; ETHYLCARBAZOLYLALALINE; VESICULAR ASSEMBLY; PHOTOENERGY-HARVESTING SYSTEM;

D O I：

10.1007/BF00807706

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A novel unnatural amino acid, L-3-(3-N-ethylcarbazolyl) alanine, was synthesized and used for synthesis of a chiral dialkylammonium-type amphiphile. The synthetic amphiphile formed a vesicular assembly in aqueous dispersion showing gel-liquid crystalline phase transition around 25 degrees C. The bilayer membrane composed of the amphiphile was nearly free from excimer as evidenced by fluorescence spectroscopy.

引用

页码：311 / 316

页数：6

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