THE STEREOSELECTIVE SYNTHESIS OF CYCLOMALTOPENTAOSE - A NOVEL CYCLODEXTRIN HOMOLOG WITH DP-5

被引：49

作者：

NAKAGAWA, T

UENO, K

KASHIWA, M

WATANABE, J

机构：

[1] Department of Chemistry, Yokohama City University, Kanazawa-ku, Yokohama, 236

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 12期

关键词：

D O I：

10.1016/S0040-4039(00)73196-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A key intermediate 15 was prepared via successive glycosidations of 1,6-anhydro maltose derivative 8 with glycosyl donors 6 and then with 11, cyclized under a diluted condition, and deprotected to give the title compound. Every glycosidation, including the cyclization, is likely to proceed stereoselectively by participation of the N-phenylcarbamoyl group at 0-6 of 6, 11 and 15.

引用

页码：1921 / 1924

页数：4

共 18 条

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