SELF-ASSOCIATION OF MONOHYDRIC ALCOHOLS IN WATER - COMPRESSIBILITY AND INFRARED-ABSORPTION MEASUREMENTS

被引：126

作者：

DANGELO, M

ONORI, G

SANTUCCI, A

机构：

[1] Dipartimento di Fisica, Universita' di Perugia, I-06100 Perugia, V. A. Pascoli

来源：

JOURNAL OF CHEMICAL PHYSICS | 1994年 / 100卷 / 04期

关键词：

D O I：

10.1063/1.466452

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The infrared absorption spectra of aqueous methanol, ethanol, 1- and 2-propanol, t-butanol, and n-butoxyethanol in the region of asymmetric and symmetric C-H stretching modes (3200-2800 cm(-1)) have been measured at 25 degrees C as a function of alcohol concentration in the whole cosolvent mole fraction region. Measurements of adiabatic compressibility were also performed on the same water-alcohol solutions at 25 degrees C. The two sets of experimental data are compared and discussed in terms of a possible mechanism of molecular aggregation in the various regions of alcohol concentration.

引用

页码：3107 / 3113

页数：7

共 28 条

[11]

FRANKS F, 1973, WATER COMPREHENSIVE, V2, pCH1

[12]

FRANKS F, 1966, REV CHEM SOC, V2, pCH5

[13]

Glew D. N., 1968, HYDROGEN BONDED SOLV, P195

[14] VOLUME PROPERTIES OF AQUEOUS-SOLUTIONS OF TERT-BUTYL ALCOHOL AT TEMPERATURES BETWEEN 5 AND 25-DEGREES-C [J].

HVIDT, A ;

MOSS, R ;

NIELSEN, G .

ACTA CHEMICA SCANDINAVICA SERIES B-ORGANIC CHEMISTRY AND BIOCHEMISTRY, 1978, 32 (04) :274-280

[15] A STUDY OF LOCAL-STRUCTURE FORMATION IN BINARY-SOLUTIONS OF 2-BUTOXYETHANOL AND WATER BY RAYLEIGH-SCATTERING AND RAMAN-SPECTRA [J].

ITO, N ;

FUJIYAMA, T ;

UDAGAWA, Y .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1983, 56 (02) :379-385

[16]

LARA J, 1981, J SOLUTION CHEM, V10, P465, DOI 10.1007/BF00652081

[17] PARTIAL MOLAL VOLUMES OF BUTYL ALCOHOLS AND OF RELATED COMPOUNDS IN AQUEOUS SOLUTION [J].

NAKANISHI, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1960, 33 (06) :793-797

[18] ADIABATIC COMPRESSIBILITY AND STRUCTURE OF AQUEOUS-SOLUTIONS OF ETHYL-ALCOHOL [J].

ONORI, G .

JOURNAL OF CHEMICAL PHYSICS, 1988, 89 (07) :4325-4332

[19] ADIABATIC COMPRESSIBILITY AND STRUCTURE OF AQUEOUS-SOLUTIONS OF METHYL-ALCOHOL [J].

ONORI, G .

JOURNAL OF CHEMICAL PHYSICS, 1987, 87 (02) :1251-1255

[20]

Onori G., 1987, Acoustics Letters, V11, P20

← 1 2 3 →