INFRARED-LASER ENHANCEMENT OF THE REACTION OF SULFUR-HEXAFLUORIDE WITH SODIUM VAPOR

被引：4

作者：

AGAM, U

EYAL, M

GRABINER, FR

机构：

[1] Department of Chemistry, Tel-Aviv University, Tel Aviv

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 68卷 / 01期

关键词：

D O I：

10.1016/0009-2614(79)80062-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The vibrational energy dependence of the rate of the gas phase reaction of Na with SF6 has been determined in a diffusion cloud experiment using CO2 laser excitation. The conversion efficiency" of ca. 40% for vibrational energy suggests a preference for vibrational over the translational energy when compared with "prior" statistical expectation. © 1979."

引用

页码：35 / 39

页数：5

共 17 条

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GRABINER, FR
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FLYNN, GW
[J]. CHEMICAL PHYSICS LETTERS, 1972, 17 (02) : 189 - 194
[8] Hartel H. V, 1930, Z PHYS CHEM B, VB11, P97
[9] DEPENDENCE OF REACTION-RATE CONSTANT ON REAGENT EXCITATION - IMPLICATIONS OF DETAILED BALANCE
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LEVINE, RD
MANZ, J
[J]. CHEMICAL PHYSICS, 1976, 12 (04) : 447 - 461
[10] LASER FLUORESCENCE STUDY OF EQUILIBRATION OF EXCITED VIBRATIONAL-STATES OF SF6 DURING SF6-RARE GAS COLLISIONS
KNUDTSON, JT
FLYNN, GW
[J]. JOURNAL OF CHEMICAL PHYSICS, 1973, 58 (04) : 1467 - 1472

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