INFRARED-LASER ENHANCEMENT OF THE REACTION OF SULFUR-HEXAFLUORIDE WITH SODIUM VAPOR

被引：4

作者：

AGAM, U

EYAL, M

GRABINER, FR

机构：

[1] Department of Chemistry, Tel-Aviv University, Tel Aviv

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 68卷 / 01期

关键词：

D O I：

10.1016/0009-2614(79)80062-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The vibrational energy dependence of the rate of the gas phase reaction of Na with SF6 has been determined in a diffusion cloud experiment using CO2 laser excitation. The conversion efficiency" of ca. 40% for vibrational energy suggests a preference for vibrational over the translational energy when compared with "prior" statistical expectation. © 1979."

引用

页码：35 / 39

页数：5

共 17 条

[11] INFRARED-LASER ENHANCED REACTIONS - TEMPERATURE RESOLUTION OF CHEMICAL DYNAMICS OF O3 + NO REACTION SYSTEM
KURYLO, MJ
BRAUN, W
XUAN, CN
KALDOR, A
[J]. JOURNAL OF CHEMICAL PHYSICS, 1975, 62 (06) : 2065 - 2071
[12] EFFECT OF REAGENT ENERGY ON CHEMICAL-REACTION RATES - INFORMATION THEORETIC ANALYSIS
LEVINE, RD
MANZ, J
[J]. JOURNAL OF CHEMICAL PHYSICS, 1975, 63 (10) : 4280 - 4303
[13] SOME CONCEPTS IN REACTION DYNAMICS
POLANYI, JC
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1972, 5 (05) : 161 - &
[14] POLANYI M, 1932, ATOMIC REACTIONS
[15] DEPENDENCE OF REACTIVITY ON INTERNAL AND TRANSLATIONAL ENERGY IN K+SF6, CCL4, AND SNCL4
SLOANE, TM
ROSS, J
TANG, SY
[J]. JOURNAL OF CHEMICAL PHYSICS, 1972, 57 (07) : 2745 - &
[16] TROTMANDICKENSO.AF, 1955, GAS KINETICS, P219
[17] THE SODIUM FLAME REACTIONS
WARHURST, E
[J]. QUARTERLY REVIEWS, 1951, 5 (01): : 44 - 59

← 1 2 →