Titanium particle-reinforced glass ceramic matrix composites were prepared by sintering under an Ar atmosphere titanium particles (Ti(p)) and the glass powders 45ZnO-15PbO-40B2O3 (MOI%) (ZPB) for the ZPBT composites and 48.8SiO2-48.8CaO-2.4B2O3 (SCB) for the SCBT composites. Each composite was characterized by scanning electron microscopy, energy dispersive spectroscopy, X-ray diffraction and differential thermal analysis. In order to modify the interfacial strength of the composites, glass matrices with different amounts of TiO2 (TZPB and TSCB, 7 and 2.1 mol% TiO2, respectively) were prepared. TiO2 allows the formation of a continuous interface between Ti(p) and the TSCB matrix and the modification of the interfacial equilibrium between Ti(p) and the TZPB matrix.